1990-03-10 — Page 31

華僑日報 All

報日僑華

六期星日十月三(〇九九一)年九十七國民華中

(31)育教日四十月二年午庚谮夏

Examples:-

Bark

• Profit on Consignment

1990 中學會考預習專欄

明德出版社

MILL & DALE PRESS

It is the Account Sales given by

Kwok's Department Stores to Mr. Lee.

Kwok's department Stores Yuen Long.

12/1.Consignment-

Insurance

Consigament

3,000

1/1 Goods sent on

31/1 Consignee-

Consignment 100,000)

Salos

150,000

3/1 Bank-

Insurance

3,000

Consignment of Furniture (Ne. Aİ23) sold on behalf at Loe's Company.

• On Receipts of Account Sales

Consignment

31/1 Consigne-

Carriage

1,000

Selling

$

$

Sales per attached cutells eac

description

50,000

1/1 Goods sent on

Consigament 100,000;

31/1 Consignoo-

Salos

Expensas 2,000 Commission 5,000

150,000

31/2011. Đ

Paymon*5

3/3 Bank-

Transportation (Carrlage)

·10,000

Insurance

3,000

Accounting (23)

Consignment (P&L)

39.000

Sales Experses

Consstun 5%

2,000 2,500 14,500 |

31/1 Conslyngo-

150,000:

150,000

Carr lage

1,000

Balance due for walen payments

enclosed

Selling

35,500

Expenses

2.000

Coral'ssion 5,000

S

Goods Sent on Consignment

31/ Trading A/C 100,000 11 Consignment 100,000

M. T. Kwok

Accounting Treatment in the Consignor's Book (Mr. Kwok's Book)

Consignment. Accounts

i consormort of goods is the relation between the owner of the goods the consignor) ard ms agent (the conafgree) who agrees to sell, collect. The debis and store the goods on benalf of the owner. Feriodically, the agent. will send report, Account Sales, to the dener, teferating him the summary seles with the rebant. of expenses and Commission changed: There are. two kinds of commission, ordinary and del rudere Commission. Del Credere commission Bears the additional Commission charged by the consignee becouse the consignee undertakes to bear the bed debts incurred Lider the doasserment.

Goods sent to consignee (Mr. Lee) from consignor. (Mr. Kwok)

Consignment

$

14 Goods sent ch

Consignment 100,000

Goors Sant on Consignmont

Constgree (Mr. Loot

$

Trading Account

31/1 Consignment 150,000 3/1 Consignment-

Carriaga Saling

1,000

Purchases

Less:Goods sent on

Expanses 2,000 Commissor 5,000

Constanmont 100,000!

Receipt of Cash from Consignee

Consignee. Lee?

$

$

|1/1 Coastynment | 100,000

150,000

31/1 Consignment 150,000 3171 Consignment

Carriage Seling

Expenses 2,000 Conmiss lon 5,000

142,000 150,000

1.000

3/2 Bank

Consignor's Expenses incurred:-

Consignment

3/1 Sonx-

Insurance

and

1/1 Goods sect on

Consignment 100,000).

3,000

-Account Sales:

It S 1 statement given by the consignee to the consignor snowing the summary of trading results, i.e. sales. proceeds, expenses and charges commission.

1990 中學會考預習專欄

明德出版社,

MILL & DALE PRESS

3/2.Consigree

(Mr. Lee)

142,000

הנוב

PAL

Bank

10/1 Consignor-

Carriage

1,000

50

Selling

Expenses

2,000

Issue of Account Sales and receipts

of sales proceeds

Bank

5

31/1 Consignor~

55109

$50,000

10/1 Consignor-

Carriage

1,000

Salling

Expenses

2,000

10/1 Bank~

Consignor (M, Kwok!

S

3/1 Bank-Salus 150,000

Carriage 1,000 Selling

Expenses

2,000

31/1 Commission

recelved

5,000

Commission Received

3171 Consignor

(Mr. Kwak)

5,000

Gross Profi profit an

Consignment

• On Remitting the proceeds.

Consignor (r. Kwoki

$

39,000

10/1 Bank-

31/1 Bank-Salas

150,000

Accounting Treatment in the Consignee's Book (Mr. Lee's Book]

• Expenses incurred by the consignee in respect of the consignment

Consignor (MC, KweM)

*મુખ સયુક Selling

1,000

Expenses

2,000

31/1: Commission

Received

5,000

2/2 Bank

142,000

150,000

150,000

10/1 Bank-

5

Carriage 1,000

Selling

Expensos

2,000

8.3 Iron rusts, faster in salt

because salt water is 3 het Ler electrical conducting, medium.

water

(a) Which of them wrli NOT displace

nydrogen from dilute acids?

Iron hall comand

8.4 Tron rusts faster

acidi

(b) which of the stable hydera

form the most

H

solutions

Decause accelerates the pss of electr by iren to formed a") ions.

Chemistry (23)

8.5 Iron does not pat

contact with a metal sabove it: ir the E.C.S. e.g. di

8.6 ir

15 10

R. Chu

coat ECS,

faster if it is in metal below it in

3.7 The diagram below helps explain

what happens during iron rusting.

UL 12 (Continued)

6. Dry cel

6.1.14

a convengaat slunce of

contenk

hijn

O conter+

02 content high

6.2

below.

virta set

5

mega

Ctn Gridiso Nyt hon. C. powder (1

It nedtrar internal resistance)

Maurer of Zhutz wad de2C1

man odactrolytel

Zac Cap the twẹ paich

6.3 The rel reactions in a day call in

USA are:

At merket Zr disolves in the

Arty!

At alamoder

electmivie paste.

6.1 Differences mustejtames of a

had used to walt

Pew

Now dry cell

fa) Po do i

Usnd dry cell

(a) 2'1 case is

corruded anc Domes thinner.

(b) True powertra

(b) The powder

bik.

mixture

lincones grey.

(c) The paste in (c) the paste may

Wet.

7. Corrosion of Metals,

7.1 Corrosion

dr cup due to Toys water.

any metals due to thwhst.incas Pat, Pan. swisstanges ntwer

12

mcide lion :!

7.3

in

Fi

st

y༼ ཀྟྭཱ{ས

41.

Kid Fever is Sepp and aparten stampey onto the

WW 100

isper.

8. RusLint of Iron

8.1 1 Conesian of

permante Patan

fle rust

Comparti, ly

a pontective

more

iran rusting. reddish-brown and "epresented

8.2 1m Bes! only in the presence of

both air and water.

Catrodic

POP.

1&1

10%

(a) The prin

rusting is process.

dros et

-iron

plate

Cathodic area

131

fegésion in aren trochemical

[b] the part of tror far f

water drop acts as the he

while the part of ares

near the edge of the water drop acts

the cathodic arca because water hear the edce contains relatively more dissolved air.

(e) First stage reactions

At the anodic area:

Fatti

Fatal - Pe

faxidation)

At the cathodic area:

ts)

282002) + 46 ~~~ 200 (29) (reduction)

The reactions above will be there are in water ta

increased if dissolved ions increase its corductivity.

{d} \lectrons flow from the anodic area to the cathodic arow inside the iron plate.

(e) 2nd stage reaction

(1) Oxidation of re2*(ag) to

(aq) by dissolved Dạt

(aq) + ©y{3} = 260

(2) Formation .of iron(II)

hydroxide

(aq) +30 (aq)

on standing

hydrated iron(111) oxidé (rust)

8.8 Methods of Preventing fron Rusting

(a) Grease/ail

(b) Paint/[nanel/Plastic coating (c) Tinelating

(d) Galvanising tron (Zone-plating!

(e) Sacrificial Corrosion

(4) Stainless

steel

containing high percentage of Or and Ni.

Question 13.1

* 2), M. A, E, F, Ca, Mg, go t symbols for the eloments, vht th Larger This wide in the depetivana Serge

!!

at 1 da brontomegal See pos

wowed ye being that boost rop five,

4

pod sing

for the lease stage cxide?

al Which of them is most likely

free in natura? (e) which of them could have its oxide reduzed by carbon but not by hydrogen?

fter some were chi

real strip -gel-plate

petri dis

following results

Observation

Gel gear magnesium strip{

1

romagnesium

and of

|| Hrod-zinc

Ign-leadi

Πρ

iu

Iron-copper

Gel eco from all tip turno blue.

() mixtures of aluminiuri

Trant11) axide ard aluminium(11) oxide and iron are heated separately, in which mixture will there be a reaction and Why? Give an equation of the reaction. (g) What would you expect to happen if з little powdered zinc is slowly added into an aqueous solution of silver nitrate and the mixture is well shaken? Giver an ionic equation of the reaction,

(h) Name a meta in the above series which is usually extracted from its molten chloride by electrolysis. (1) Ordinary aluminium metai shows little chemical reactivity towards many of the reagents such as water, dilute acids, etc.. although it has a rather high position in the Reactivity Series.

Explain briefly why this '$ 20.

Question13-2

PUBLIC

placed in

inside a porous put.

The pot with its content is then placed in beaker containing a copper plate in comper(II) sulphate solution, When closec, a current is register ammeter.

Key

Ammeter

(a) that 35 the purpose ot adding phenolphthalein indicatospe the

gel?

purpos

fadding

(b) What is the

potassium hexacyanorete(11 solution into the gefas (c) Referring to the in

explain why the go

any pink. (d) Referring to the ult in Iv, explain why geturns blue.

(e) In which 300 Would the. iron

corrodereádily?

brite the ionic equations showing the charges of iron during its

on.

(F) Describe how the zinc coated C'

iron (galvanized iron) protects it from.corrosion even when the zinc coat is broken.

Solution to Q.13.1

sy 15 the

(a) Cu or Ag:

it 15 because reactive tran hydrogen..

less

(b) because it is the most reactive

one of the elements listel.

(c) Ag because t

རྟུ

east

reactive one of the elements Fisted.

Zine rod

(d) Ag.

(e) Zn.

reaction

wild

Copper plate

1 M Z1nc

sulphate solution

1 Copper)

Sulphate

r - Besker

Paus pat

salutlan

(a) State the direction of the electron

flow in the external circuit. Explain your answer.

the (b) write the ionic equations of

reactions at the zinc rod and the copper plate rospectively.

(c) Why must the put be porous?

[d] [ what direction would the

Spuste

pats Chrough

porous pot?

Explain your answer briefly,

the

(e) Mould taene De any change in the

color intensity üf

sulphate solution?

coppe~(10)

Explain your answer briefly.

(0) Do you think the reaction above is quivalent to placing a zine rod in camper(11) sulphate solution?

its (g) If the copper plate changes

auss by 2 y at the end of the experiment, what would be the Change in mass of the zinc rud?

(h) Describe THREE changes you would observe it the zinc rod and 1 M zinc sulphate solution are replaced. respectively by a silver rod and 1 M silver nitrate solution.

Question 13.3

t

Four pieces of iron nails. cach coupled with different metu! strip were placed ir: separate petridishes containing gel with a few drops of phen:bokthalein indicator and potassium

The xutyan fetrate solution. set-up wak shoen AS in the diagram.

|(F) A

in the 'occur Mixing in and troni oxide because aluminium, being wore reactive than iron. can reduce iron(11) oxide to tron.

241 3Fe0- 41203 + 300

(g) Zirc powder dissolves and silvery

crystals of grey

silver are deposited. This 15 because zinc displaces the less reactive silver from its solution.

Zn(s) 2A (ac)-

;-/n2 * (aq) + 2Ag(s)

(h) %.

(1) Freshly-prepared aluminium metal is very roactive chemically. Ordinary aluminium is usually covered with a layer. ni transparent through aluminium oxide which gets as a protective layer on the metal.

Solution to Q.13.2

(a) The electrons flow from Q to P.

It is because Zinc Is MISTE electropositive thar copper. and hence has a stronger tendency to lose electrons.

(b) At the zinc nodi

Zn(s)

Zn2+(aq)

- 2

At the copper plate:" Cu2+(aq) + 2e -----

Cufs)

(c) The pot must be porous to allow the two electrony to make electrical Contact:

(d) The sulphate Fons would pass from the outs de to the inside of the porous pot.

This is because there is an excess of positively-charged

Dank

342 Consignor

(Mr. Kwok) 142,000

(7n2+) inside the pot which thus negatively-charged

attract

the

sulphate ions ($0) into the pot.

(e) Yes. The blue colour fodes off because there is a decrease in the concentration of copper(II) ions due to its deposition on the copper plate.

(f) Yes. The overal reaction is:

Zn(s) - Cu2+(aq) →→ Zn2+(aq) + Cu(s)

(g) M(Zn) - 65.4 g mal

2

MEC 63.5 g -1 n(Cu) deposited = 63.5 mol

According 10 the equations

-202+(aq)

following

+ 2e

Znts! cu2*(aq) + że ̄-→ Cu(s)

n(Zn) dissolved = n(Cu) deposited.

change in mass of the zinc rad

- 65.4 × 63.5

2.06-g

(h) The 3 changes observed are:

(1) Copper plate is dissolved. (2) Silver deposited on the silver

rod. (3) Electrons Flow From copper plate to the silver rod in the

i.e., external circuit,

the Current is reversed.

Solution to Q.13.3

(a) It is used to detect the presence of the hydroxide fons (OH) because phenolphthalein turns pink in the presence of OH" ions.

(b) It is used to detect the presence of iron(11) fors (Fe2+) because hexacyanoferrate(III) ions form a deep blue complex with iron(11) ions.

(c) This indicates that.. hydroxide ions

are present near the magnesiu

It is formed when magnesium strip. reacts with water and the dissolved oxygen.

2Mg(s) + 2H20{f) + O2(g)

· 2mg2*(aq) + 40н"{27}

(d) This indicates that iron(II) ions are present.near the iron nail.

It is formed when iron reacts with water and the dissolved oxygen.

2*(5) + 212008) + O2(9)

2fe2'(aq) + "(aq)

[[e) [rum corrode most readily in IV because iron is attached to a melal Tower in CS, i.e. Copper. The jogic equations of reactions involved are:

the

Stage 1: Fe(s): --- Fe21 (aq) + 2e ̄ Stage 2: 4re (ac)+02{g}+2\D{e}·

4Fe(aq)-10 (aq)

- Fe(OH)3(s)

Fo" (aq)+3GH ̈(aq)—-

3+

on

standing

rust (hydrated iron(II) oxide)

[(F) When the zinc coat is broken irun will be exposed to air. However, since zinc is more electropositive tran fron and has 2 stronner tendency to lose electrons to form ions than iron, so, iron remains unchanged while zinc is oxidized to zinc(11) ions, Zn2+(aq).

風南

許多爭雅劫案。

一黃伯骥道..「那些就接踵而來,故該行業的保險費

<

們可行反省過背己怎樣對待在無國旅遊時 BLEKUAKCBaluz - exe

FIRE - YZRESH~

英國人唔愛旅遊,但他們總愛選擇那

的霈)族呢?

做到獎

些扥雙溫暖和常多的地方去,最熱門的

張庭

嬬佾! 示最完 來自珠 便的配

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