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• DK] BESEMÉ@SKERK KANG 咪 IBB
sample of Bodium carbon-
ate.
育教僑華 R
18
1978
中學會考試題預習專欄
AREA
化學
(廿九)朱宏林
Chemistry (29)
Question 43
(a) Study the following block dia- gram carefully and then answer the question which follows.
CHO
can give white steamy fumes with phosphorus(V)chloride. Qis a hydrocarbon which can
decolorize acidified potas- sium permanganate solution. (1) Give t
the names of comp- ounds P, Q and R and
write down their respec-H. tive structural formulae, (11) State the reagent(s) and
the conditions for the conversion of P to Q: Give an equation for the reaction.
(ii) Mention the reagent(8)
used in converting P to R.
Give an equation for the reaction,
(iv) What would be obtained when is heated under a high pressure and a high temperature with a little peroxide as the catalyst?
Using structural formulae show how the substance can be obtained from the compound Q..
(b) The following investigations were carried out on a sample of water X from a small town and the results were recorded in the table below:-
(1) distilled
vol of soap sol- ution to for a permanent lather
When, aqueous barium chloride solution is added to a solu- tion of sodium sulphite, a white precipitate ia obtained, What is this precipitate likely to be?
Give an ionic equation for
its formation.
(11) When dilute hydrochloric acid
la added to the precipitate,
it reacts and a pungent gas
is given off. What is this
gas? Give an ionic equation for its formation.
(iii) A solution of sulphur dioxide
in water is warmed with a little nitric acid. Barium chloride solution is added and a white precipitate is formed which does not dissol-
ve when dilute hydrochloric
acid is added. What happens. to the solution of sulphur
dioxide when it is acted upon by the nitric acid? Give the equation for the reaction concerned.
(iv) What would you observe when
a solution of sodium sulphite is shaken up with bromine solution in water?
Give an ionic equation for the changes observed. Question 45
(a) Ten beakers, each of which
containe 25 cm of silver nitrate solution, are prepared. Different volumes of a sodium chloride solution are then added separately into the beakers. The weight of the precipiate formed in each beaker is recorded, The read- ings are shown in the follow- ing table:-
wt. of the
precipitate/g
vol of NaCl Beakers added/cm2
(1)
01
0.052.
0.304
0.156
0,208
0,259
0.312
0.342
-0.342
0.342
Give an ionic equation for the formation of the precipitate.
(ii) What is the minimum vol-
ume of sodium chloride. solution required to re- act with all the silver nitrate in the 25 cm solution?
(iii) How many moles of silver nitrate are there in the solution?
(iv)
how many moles of sodium
water
(2) sample X
0.2 cm
35 cm
21 cm3
(v)
(3) boiled
sample X
བྱང་འཕྱ་སྐྱེ་གྱི་སྐུ་སྐྱོ
What is a hard water'?.
(11) What chemical species
is/are responsible for the hardness of water? (111) What is meant by the
*temporary hardness'?
(iv) What is meant by the
'permanent hardness?.
Do you think the sample
X consists of temporary hardness or permanent hardness or both?
(vi) Suggest a method suitable
to remove the permanent hardness.
Question 44 (a) 2.48 g of a sample of hydrated
sodium carbonate, of formula
of
Na CnH20, are dissolved in 50 om of M hydrochloric acid and the resulting solution,is made up to 250 m2. :25 m2 this diluted solution require 20 am of a 0.05M sodium hyd- roxide for neutralising the excess acid.
(at.wt.Na=23, C=12,0=16,01=35.5
K=1
(1) Write the aquation for
the reactions involved.
(ii) Calculate the value of n,
the number of water of crystallisation, in the
chloride are required to completely precipitate the silver nitrate
present?
what is the concentration
of the silver nitrate: 5 solution?
(vi) What is the concentration
of the sodium chloride solution?
(b) The following experiments were
carried out, in order to study the conditions for rusting of iron to take place:-
nail
Call bolled water salty acidified
we tor
water water The following results were
obtained:-
Tubes
Resulta
.(A)...
no corrosion(rusting)
(b)
no corrosion
(0)
(a)
(e)
(1)
rusting
extreme corrosion
extreme corrosion
What are the necessary conditons for rusting to take place?
(11) Give an ionic equation
to show the changes the iron has undergone during rusting.
(iii) What
happens
to
the rate
of rusting in the presence of salt or an 'acid?
Explain why this is so.
(iv) Do you expect a car parked near sea will rust faster?
Rusting is in fact a redox reaction during which iron loses electrons. Using - this idea try to explain (1) why iron plated with
tin is easy to rust when the tin coat is broken?
物理
(2) why iron plated with
zinc is not easy to rust even when the zinc coat is broken?
(廿九 ) 香榮家
PHYS ICS (29)
Answers to Revision Exercise
SECTION A * - MECHANICS AND.
"PROPKUTIES OF MATTER 1.(a)(i)The graph of linea speed against time is as
follows:
Time in second
(ii) The linear ace
slope of the graph
2
ma
(Ans.)
(iii) Apply | 8. fat
100- 3(2)+2
t10 s (Ans.) (iv) Let the coefficient of
sliding friction between the
hody and the inclined plane
be u, the mass of the body be m and the angle of inclination of the plane Al be
flence the net force acting
on the body is
ngs ine ungcon8
m(gaine uge na6)
Apply Newton's 2nd Law
P ma
(gsine
3(5)2 + (3m)(5)2
50m J
+
The fraction of energy lost
200m 50m 200m
(Ans)
(i) The energy lost in this
impact will be dissipated mainly in the form of heat and little in the form
sound.
2(a) The conditions are
1. The resultant of the forces
must be zero.
2. The lines of action of the
forces must be concurrent. for, equivalently, the re- sultant moment about any point
is zerpa
Since, the non-uniform Tad AB is in equilibrium, ánd
there are three forces acting
on the rod, they are the ten
sions of the strings and the
weight of the rod, Therefore;
the forces must be concurrent
Hence the centre of masa nf
the rod can be found graphical
ly as he low
75
The Lines of action of tension Tand. Tz dre.... produced and wizeť at 0.
& must, on Ake vertical, like thresho
Ans: The centre of mass of
the rod AB is 2,5m from A. (Note : AG : GB = 1 : 3)
(c) let the reactions at P and
Che B and B respectively. (*) An shown in the force
diagram below
n = mass of the man - 75kg
mass of the planck-50kg Since the planck is in equi-
librium, the resultant of
forces acting on the planck
iszRTO
B+ B - mg - μg - 0
R1 + Ry - 750- 500 = 0
Roy
1250 (1): Also, the sun of moment about
nge one)
but
відн
Cras
10ms 80
any point must be zero,
TOU
to
100
•((10)(276) ~ u(19) (100)
Take moment about P.;
B(6) mg (5) - Mg(3); = 0) R2 (5)-(75)(10)(5)–(50)(10)(3)
6
= 0.5 (Ans.)
(b)(i)Take the direction to-
wards right as positive, lat the velocity of the body at B be v.
Apply 12
= 2A8.
= 2(2)(100)
-1
400
Y = 20 ma
Momentum before impact -m(20)
Movientam after Impact
(n +
3m)v!
where v' is the final velocity
20m2 « (m43m) v.*
5 ma (Ana.)
-1
(ii) Total energy before
impact m(20)2. - 200m J Total energy after impact
875 N
{ans.)
From (1),
M
1250 1250
H2
www
875
375 N (Ans.)
(ii) Suppose the planck will tilt when the man is x meters from B. Hence, the reactio
Fon
at P, By = 0.
Take moment about Q
R1=0
Mg (3) mg (QB (50)(10)(3)-(75)(10) (3-x)-
* 1
Annt. When the man ia 1 m
from B.
(i) The
velocity
ratio of
the system is 8.
(11) weight of the block
-(7200) (0.01) (10) = 720N The efficiency of the system
M.A. V.R.
x 100
= 90% (Ang.) (iii) since.
by Load Workdone
Workdone by effort
efficiency = 90%
720 x 4 Workdone:
720
100
x 100%
8
100%
x 100% 90%
Workdone by effort
3200 J (Ans.)
The M.A, of the system
720
-7.2
-100
The tension in the cord
connected to the iron block
7.2 x 75N
540. N
The tension in the cord is
less than that in (a) because
of bouỹant farer.
Houyant force,
720N - 540N.
180N
(density of liquid) x 8
x (volume of the iron block) (density of liquid) x (10) x (0.01).
-(0.1) x(density of liquid)
Density of liquid 1800 kg m-3
SECTION B
HEAT, LIGHT SOUND AND WAVE MOTION
4(a) Quantity of heat absorbed by the alloy of mass (M+2}}kg if the temperature is incre- ased by 1 c
≈ 1000M + 550 (2M)
Joules
Heat required to raise the
temperature of the alloy per
kg through-1°c ·
(Specific heat capacity
the alloy)
2100M
73H
- 700 J
The specific heat capacity
of the alloy
alloy
■ 700 J kg
(Ans.)
(b) Let the temperature of
the bunsen burner flame be t°C.
Heat energy given out by
the sphere
(0.3)(700)(t = 35)'' ́s
llent energy gained by water
and calorimeter
= (1.98)(4200) (35-15) (0,2)(420)(35-15) 168000 J
(0,3)((700)(t-35)
168000
t = 835 (áns,).
the temperature of the bunsen burner flame is 835€
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