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小丑

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हउ

邪思明(聖伯多税小学)

Very dilute IND, gives H2 with Mg only.

(c) They liberate

сог 2-

from the

1989 中學會考預習專欄

carbonates(CC,

hydrogen-

德出版社

MILL & DALE PRESS

Chemistry (3)

B. Chu

Unit 2: Revision notes on Acids, Bases

and Salts.

1. Acids

1.1 An acid is a substance which, when dissolved in, water, produces hydronium ions (or hydroxenium), H30, as the

only cations.

[_e.g!= dict(g) + H20(£)—H2O* + £17%

fhus all acidic properties are due to the presence of the hydronium Tons(4,0*).

1.2 The basicity of an acid is the number of ionizable for replaceable) hydrogen atoms molecule of the

re acid.

Monobasic

INO, acids: HCI, CH,COOH, etc. Dibasic acids: F250 C03 H12SO2, etc.

2.3.

Tribasic acids: H2PD, etc.

1.3 General properties

of

dilute!

aqueous solution of acids

(a) They usually have a sharp, sour-

taste.

(b) They turn litmus (or PH) paper red. methyl orange red phenolphthalein colourless.

(c) They neutralize bases.

or

(d) They give, H, gas on reacting with matals above hydrogen in the Retal Activity Series.

Meto)+2H (2q)--Metal ion-Hy(g) e.g. Zu{s)+2H (aq)--/n2*(ag)+H2(e)

N.B. Being an oxidising acid ordinarily)

dilute NO, sives NO or NO, gas instead of H when reacted with vietals, both above or below the hydrogen in the Activity Series.

Economics (3)

Alain Li

HONG KONG'S ECONOMIC DEVELOPMENT The history of Hong Kong's econo development

be divided into

stages:

can

A. Before the Opium War a fishing

village

In the very beginning, Hong Kong was a fishing village. People made their living by fishing.

B. After the Opium War — an entrepôt After being ceded to Britne 1842, Hong Kong became an entcerot Through.

Kong 1long

European products were brought to China.

Chinese products were brought

Europe Hong Kong provided services of warehouses, docks wharfs to the traders.

an

C. After the Second World War

industrial city Following the end of the Séenne World War in 1945, the communists took control of China, Many rich business men and hard-working workers came to Hong Kong, bringing

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carbonates(HCC).

C032~(s)+21*(aq)—H2O{} }−CO2(g)

·HCO2 ̄{s} +H* (aq) →H2O{!}+002{3}

(f) They are electralytes and conduct.

electricity readily.

2. Bases

2.1 A base is a substance which reacts with an acidic to give water and a salt only.

2.2 Bases are mostly hydroxides of metals. e.g. Cu, Zn(OH), etc.

the oxides or

Most of them are insoluble in water. 2.3 4 soluble base is called an alkali, When it dissolves in water, is produces the hydroxide ions. CH(aq) as the only arion.

Thus, all the alkaline properties are due to the presence of the hydroxide ions, OH (o).

e.9. K20(5)+120(£) -- 2k* {@q}+20H°(aq) NaCH(5)+R291 ( ) — Na*(aq)+OH°(aq)

2.4 General properties of Bases

(a) Alkaits have a bitter taste and

feel soapy for slippery).. (b) Alkalis turn itmus for 2)

blue,

orange ine thy - paper

vellow or phenolphthalein pink. (c) Strong alkalis (e.g. Nabii and KOH) gives H2 on reacting with the amphoteric metals. (e.g. Al, 7n, Pb and Sn) on warming. 2.g. Zn(s)+20H(aq)+21120{{}

D.

---→

2.

(d) Alkalis liberate 'N gas from

ammonium salts on heating.

NHA

+

(e) All bases neutralizes acids. (F) All bases are electrol: can conduct electricly. (g) Alkalis

te

and

can

of capital

skills

sides, the Korean War

1954 Roofing an international ban ondet China forced Hong Kong to give up its entrepôt trade. Hong Kong developed its

第50

industries as a new way of earning ney. The industries first started

textile and plastics. In the 1970s fabricated metal products Natches and clocks, toy, precision and optical instruments, an genuine and imitation jewellery developed rapidly.

1980' an industrial, commercial and "finncial centre

ari

In the 1980's, Hong Kong has become international, industrial, commercial

centre and financial owing to the following reasons: 1. Central geographical position

hesa Hong Kong

-central geographical position in South East Asia, far more central than Tokyo ur Singapore has. This is important to communication and transportant.

Immediate proximity to China

Che requires enormous funds to ber

economic

coastrugliame Because of its fmedige pleximity to China,

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precipitate the insoluble metal hydroxides From

their corresponding aqueous solutions.

Metal ion(ag)÷0k ̄(aq)

insoluble metal hydroxide N.B. Ampheteric metal hydroxides (e.g.

Zn(OH)2 Al(OH), Pb(OH), and Sn(0) can dissolve in excÊSS alkalis

Dy forming scluble complexes. e.g. Zn(OH),(s)+20H" (aq)—Zn{0}),~~(ar)

zincate ion

3. The pH scale 3.1 A strong acid is one. which is completely ionized

sive the hydronium ion in its dilute aqueous solution.

e.g. ICT, H250, HNO3-

A weak acid is one which is only slightly or partly ionized in water. 0.9. CH COCH(ervatioic acid), ga

3.2 A strong alkali is one which is fully dissociated or ionized to give the hydroxide ions in its dilute aqueous solution. 9.g. NaOH. KO!.

A weak alkali is one which is only partly ionized in water.

29. NH3 (7) + H2 (£) —N12*(ac)+UF (aq) 3.3 pH value of a solution=-log;piH30*] where [H0] is the concentration of H20* ions in mol dm3.

3.4 The pH scale is a scale to compare the strength of acids and, alkalis in a scientific and quantitative way.

10-12 12 13 14

creating «idity

do ossing allativity

On this scale, palkaline solution

neutral solution placidic solution The pH of a solution is measured readily using pH meter.

4. Neutra 2013 on

4.1 Neutral za reacticed whiche

"oid-reacts with

give water and at only.

Hong Kong has attracted a lat c foreign Financial corporations.

and

3. Industrious,. mobile

adaptable workforce Hong Kong workers tend to work long hours and can adapt to new production methods and products. Besides, labour mobility is high because Hong Kong is so compact geographically and there are few institucional barriers movement.

4. Economic

四期星 日三十月十(八八九一)年七十七國民華中 ( 18 )

Acic Base -käter + Salt

4.2 The essential. process neutralization is the combination of

the hydromum icas(130*) and the oxide Fans(02) or the hydroxide ions(@H") to

form water.

2430+ + 02 ̄(5) ~~+ 3H20 or, H20*+ Dif(s) --- 2H2O

A salt is resulted tor. 4.3 Energy is usually evolved in the farm of heat during neutralization.

5. Salts

5.1 A normal salt is obtained when the replaceable hydrogen atoms of an acid is totally replaced Ly Petal {or ammonium) ions.

e.g. Nacl. K2504 200

5.2 An acid salt is obtained when the replaceable hydrogen atoms of a dibasic or tribasic acid are partly replaced by a metal for ammonium) ions.

e.g. Na4504, KP, KPO, etc.

5.3 An acid salt can be converted to J Normal salt by further replacement of. the hydrogen atoms in the acid salt. e.g. HaHSO+

5.4 A basic sait is obtained if the hydroxide (on of a base is only partly neutralized by an acid. It is a salt containing hydroxide ions.

e.g. Mo(OHIO). Duc, Cu(OH), etc.

5.5 Many salts do not give neutral solution when dissolved 10 water because they are bydrolysed to give new products which affect the pH of the solution.

(a) Salts formed from strong acids and strong alkalis dre nos hydrolyse ard their aqueous solutions have a μH~7. e.g. NaCl, K2SU1, etc. ́

(b) Salts formed from strong acids and weak bases are hydrolyed and their aqueous solutions have a pH 7. e.g. WH CUSO, etc.

Salts formed weak acids and strong alkalis are hydrolysed and their

shipbreakings

never i 1961.

solutions have a pH>7. m.g. Na200,, Cyccona. etc.

Owing to the hydrolysis of salts, even some acid salts would give ar alkaline solutions when dissolved in water, e.). NUHCO, (aq) is alkaline.

5.6 Solubility Rules of the salls

(a) All salts of Group

ammoniuw are soluble.

morals and

(b) All-nitrates are soluble, (c) All halides are soluble except

those of Ag, Hg and 252+ (N.B. PbC12

is very soluble in hot water.i

(d) ATT sulphates are scluble except

2+ those of Ba2+, P52: and Ca

(e) All carbonates are insoluble except

those of Nat, R and NH2*• 7) All acid salts are soluble. 5.7 Methods for preparing salts

For soluble salts - 3 Bechids I.. Dilute acid + metal →salt ella

The metal oust be above H in tre Metal Activity Series. *.g, My+H250 - Musi

11. Dilute acid Base sa}{ +

2.g. Waðн-HNO2 -NRO #Holi

carbonates

II. Dilute acid

---salt +

+

e.y. 2001+Caco, Ca£y={O}}

For Insoluble salts

IV. Precipitation reaction -- By mixing.

2 aqueous solutions, une containing the cations and the riter the anions of the insoluble salt.

8.g. Ag(aq)-Natl{aqi

--AgC1 (5) +N&#02(@q)

(or, Ag"(aq)+C) ̃(aq)--+ agrits!)

For Both soluble and insoluble binary salts

V. Direct combination

a.g. Fe Sx-Fes

re-rolling, were declined since

2.

AUVANTAGES OF THE LIGHT INDUSTRIES For liong Kong, light incidin obvious advantages:

1. Requiring small

Poor management.

As small firms are often tamiy firms, they may not always make the best appointments Le managerial positions.

PROBLEMS OF HONG KONG INDUSTRY At present, Hong Kong industry faces the following 3 problems:

1. Competition

They do not take up

per dollar of cutpe

2.

Start on a small scale

to

They can be started on a smat1 scale, using little space and requiring little capital.

3.

Continuation on a small scale: They can continue

1.2.

J ว

policies of free enterprise and free trade Laissez-faire is the underlying principle of Hong Kong economy." This gives people greater. freedom in economic activities and attracts foreign investment.

5. Low earnings and profits tax

rates

tax

Low carrings and profits rates give people high incentives to Work and 1.0 investi

INDUSTRY IN HONG KONG

A conspicuous feature .OF. the development of industry in Hong Kong has been the concentration on light industries. Heavy industries, such as

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There have Deen increasing Competition from other developing countries such as South Korea. Taiwan and Singapore, where wanes tévels are generally lower. Trade restriction

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.:

As a result of the above problems, hong Kong industry is wore diversified, and So are the markets for exports. Hong Kong industry is producing Kone sophisticated and higher quainty products.

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